- Friedrich August I (1806-1827) (Elector of Saxony 1763; Grand Duke of Warsaw 1807-13) m. Amalie of Zweibrücken-Birkenfeld
- Anton I (1827-1836) m. 1.Maria Carolina of Savoy 2. Maria Theresia of Austria
- Friedrich August II (1836-1854) m. 1.Archduchess Marie Caroline of Austria 2.Princess Maria Anna of Bavaria
- Johann I (1854-1873) m. Amalie Auguste of Bavaria
- Albrecht I (1873-1902) m. Carola of Vasa
- Georg I (1902-1904) m. Infanta Maria Anna of Portugal
- Friedrich August III (1904-1918) m. Archduchess Louise of Austria
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